Ozonación catalítica heterogénea de fenol utilizando catalizadores de hierro en un reactor de lecho percolador
The use of continuous reactors for heterogeneous catalytic ozonation is yet to be investigated in order to develop a viable technology for industrial applications. This paper presents hydrodynamic and degradation studies on the use of a co-current down flow trickle bed reactor for heterogeneous cata...
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| Autores principales: | , |
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| Formato: | Online |
| Lenguaje: | spa |
| Publicado: |
Universidad de Costa Rica
2020
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| Materias: | |
| Acceso en línea: | https://revistas.ucr.ac.cr/index.php/ingenieria/article/view/39236 |
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| Sumario: | The use of continuous reactors for heterogeneous catalytic ozonation is yet to be investigated in order to develop a viable technology for industrial applications. This paper presents hydrodynamic and degradation studies on the use of a co-current down flow trickle bed reactor for heterogeneous catalytic ozonation of phenol (as model pollutant) over Fe-Diatomite pellets and Fe-coated glass beads. It was found that the reactor can operate under trickle or pulsing flow regimes, promoting mass transfer augmentation. Residence time distribution data, fitted with n-CSTR and axial dispersion (ADM) models, showed low axial dispersion and high flow distribution. Just the Fe-diatomite pellets showed important phenol adsorption (16 %). Degradation experiments demonstrated that phenol conversion was substantial when using both catalysts, up to 19,7 % pollutant conversion with liquid-phase space times of just 6 s. Compared to direct ozonation, the use of the Fe-diatomite pellets and Fe-coated glass beads enhanced the reactor performance by 48 % and 23 %, respectively. It was confirmed that mass transfer is an important factor that restricts this reaction system performance; consequently, further improvement in mass transport rate is necessary for system optimization. |
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